000 02388nam a2200277 4500
001 393927
090 _a393927
100 _a20160523d2012 y0pory50 ba
101 _aeng
200 _aDevelopment and validation of a method for individualization of middle petroleum distillates and kerosene ignitable liquids
_bRecurso eletrónico
_fJ. Graham Rankin, Peter Harrington
210 _a[Rockville, MD]
_cNational Criminal Justice Reference Service (NCJRS)
_d2012
215 _a1 CD-ROM
_d12 cm
300 _aResearch report submitted to the U.S. Department of Justice (Award nr. NIJ 2008-DN-BX-K146). Ficheiro de 1,54 MB em formato PDF (109 p.). Resumo inserto na publicação.
330 _aThis project applied target compound analysis from high resolution Gas Chromatography/Mass Spectrometry (GCMS) utilized for gasoline individualization to Medium Petroleum Distillates (MPD) and kerosene which may be used as accelerants in arson cases. A major goal of this project was to establish analytical tools that provide a statistical evaluation for forensic comparison between ignitable liquid residues in fire debris and ignitable liquids in the possession of a suspect. Classifications based on two-way profile and target component ratios were compared. For kerosene, the Projected Difference Resolution (PDR) mapping technique was applied to measure the quantitative differences among the Ignitable Liquid (IL) samples by their GCMS profiles. Fuzzy Rule-building Expert Systems (FuRESs) were applied to classify individual ILs. The FuRES models yielded correct classification rates greater than 90% for discriminating between samples. PDR mapping, a new method for characterizing complex data sets was consistent with the FuRES classification result. For MPD, the Kendall’s-tau metric for ‘association/no-association’ was utilized to demonstrate ‘association/no-association’ true positive rates in excess of 95% with false positive rates ~5%.
606 _aPRODUTO INFLAMÁVEL
_9343931
606 _aINCÊNDIO
_9243828
606 _aANÁLISE DE VESTÍGIOS
_9320649
606 _aCIÊNCIA FORENSE
_9321508
606 _aQUÍMICA FORENSE
_9343048
700 _aRANKIN
_bJ. Graham
_9358109
701 _aHARRINGTON
_bPeter
_9358110
955 _xOferta