The conservation of orbital symmetry / R. B. Woodward, R. Hoffmann
Idioma: Inglês.Publicação: [Weinheim/Bergstr.] : Verlag Chemie, 1970Descrição física: 178 p.; 22 cmAssunto: 349496Resumo: 1. Introduction. 2. Orbitals and bonding. 3. Correlation Diagrams. 3.1. General comments on the construction of correlation diagrams. 3.2. Precautions in the construction of correlation diagrams. 4. The conservation of orbital symmetry. 5. Theory of electrocyclic reactions. 5.1. Electrocyclic reactions exemplified. 6. Theory of cycloadditions and cycloreversions. 6.1. Cycloadditions and cycloreversions exemplified. 6.2. [2+2] Cycloadditions in the photochemistry of the cyclohexadienones and cyclohexenones. 6.3. The [2+2+2] Cycloaddition reaction. 6.4. Prismane. 6.5. [2+2+2+2] Cycloadditions. 7. Theory of sigmatropic reactions. 7.1. Sigmatropic reactions exemplified. 7.2. Sequential sigmatropic shifts. 8. Group transfers and eliminations. 9. Secondary effects. 10. Divertissements! 10.1. Cheletropic reactions 10.2. Cycloaddition reactions of Ketenes. 11. Generalized selection rules for pericyclic reactions. 12. Violations. 13. Other theoretical work.14. Conclusion.| Item type | Current location | Call number | Copy number | Status | Date due | Barcode |
|---|---|---|---|---|---|---|
| Monografias | Biblioteca da Polícia Judiciária | PJ18.D.19 (Browse shelf) | PJ26439 | Available | PJ126439 |
1. Introduction. 2. Orbitals and bonding. 3. Correlation Diagrams. 3.1. General comments on the construction of correlation diagrams. 3.2. Precautions in the construction of correlation diagrams. 4. The conservation of orbital symmetry. 5. Theory of electrocyclic reactions. 5.1. Electrocyclic reactions exemplified. 6. Theory of cycloadditions and cycloreversions. 6.1. Cycloadditions and cycloreversions exemplified. 6.2. [2+2] Cycloadditions in the photochemistry of the cyclohexadienones and cyclohexenones. 6.3. The [2+2+2] Cycloaddition reaction. 6.4. Prismane. 6.5. [2+2+2+2] Cycloadditions. 7. Theory of sigmatropic reactions. 7.1. Sigmatropic reactions exemplified. 7.2. Sequential sigmatropic shifts. 8. Group transfers and eliminations. 9. Secondary effects. 10. Divertissements! 10.1. Cheletropic reactions 10.2. Cycloaddition reactions of Ketenes. 11. Generalized selection rules for pericyclic reactions. 12. Violations. 13. Other theoretical work.14. Conclusion.
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